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Photodissociation Dynamics of CF 2 I 2 in CCl 4 Solution Probed by Femtosecond Infrared Spectroscopy
Author(s) -
Park Seongchul,
Shin Juhyang,
Yoon Hojeong,
Lim Manho
Publication year - 2020
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.12096
Subject(s) - photodissociation , femtosecond , chemistry , spectroscopy , excitation , molecule , infrared , analytical chemistry (journal) , infrared spectroscopy , photochemistry , laser , physics , optics , organic chemistry , quantum mechanics
Dynamics of photodissociation of CF 2 I 2 in solution after excitation at 350 nm. One I atom is immediately dissociated and all the dissociated I geminately rebinds to form reactant or isomer that rapidly releases I 2 molecule producing CF 2 , which bimolecularly reacts to produce C 2 F 4 .
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