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Copolymerization of Functional Norbornenes Catalyzed by Pd Complexes: Is it Living?
Author(s) -
Lee Dong Jin,
Choi Won Ho,
Kim Myungwoong,
Kim Chan Kyung,
Lee Ik Mo
Publication year - 2020
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.12056
Subject(s) - copolymer , polymerization , catalysis , monomer , palladium , polymer chemistry , living polymerization , chemistry , photochemistry , organic chemistry , polymer , radical polymerization
Copolymerization of functional norbornenes by novel palladium complexes has been successfully done. Soluble addition polymerization products with high Mn and low Đ have been obtained, which improves possible processibility. Some clues of living character of this catalytic system have been observed by kinetic studies of the polymerization and sequential addition of same or different monomers.