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RuO 2 ‐coated MoS 2 Nanosheets as Cathode Catalysts for High Efficiency LiO 2 Batteries
Author(s) -
Jeong Yo Sub,
Jang Yu Jin,
Park SoJung,
Lee Yun Jung
Publication year - 2019
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.11745
Subject(s) - cathode , catalysis , materials science , lithium (medication) , nanotechnology , coating , molybdenum disulfide , chemical engineering , chemistry , metallurgy , medicine , biochemistry , engineering , endocrinology
Despite their potential for high capacity, lithium oxygen (Li–O 2 ) batteries still suffer from the low round‐trip energy efficiency and limited cycle life, mainly due to the slow decomposition of discharge products. Therefore, developing efficient catalysts is a key issue for the practical application of Li‐O 2 batteries. Ruthenium oxide (RuO 2 ) is one of the most efficient catalysts developed thus far for lithium‐air batteries. However, the high price and limited availability of Ru prohibits its large‐scale use in practical device fabrications. Recently, molybdenum disulfide (MoS 2 ) has been actively investigated in various catalytic systems, taking advantage of its two‐dimensional (2D) structure and catalytic activities. However, the low electrical conductivity of MoS 2 limits the realization of fully operative MoS 2 ‐based catalysts on its own. In this report, RuO 2 ‐coated MoS 2 nanosheets (RuO 2 /MoS 2 ) are prepared and implemented as cathode catalysts for Li–O 2 batteries. In this hybrid structure, RuO 2 and MoS 2 complement each other; the poor electrical conductivity of MoS 2 is overcome by the nearly conformal coating of conducting RuO 2 , while 2D MoS 2 nanosheets act as excellent supports for RuO 2 catalysts and also contribute to the overall catalytic activities. These combined features result in excellent cathode performance, including improved efficiency and cycling lifetimes, with significantly reduced amounts of precious RuO 2 .