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Complementary Chromophore Decoration in NU‐1000 via Solvent‐Assisted Ligands Incorporation: Efficient Energy Transfer within the Metal‐Organic Frameworks
Author(s) -
Oh Jung Suk,
Park Kyoung Chul,
Gupta Gajendra,
Lee Chang Yeon
Publication year - 2019
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.11655
Subject(s) - solvent , chemistry , metal organic framework , chromophore , singlet oxygen , ligand (biochemistry) , adsorption , spectroscopy , photochemistry , fourier transform infrared spectroscopy , desorption , scanning electron microscope , metal , infrared spectroscopy , materials science , chemical engineering , organic chemistry , oxygen , biochemistry , physics , receptor , quantum mechanics , engineering , composite material
BODIPY‐incorporated solvent‐assisted ligand incorporation metal‐organic frameworks (SALI‐MOFs) were designed and synthesized using NU‐1000 and carboxylic acid functionalized BODIPY moieties by the solvent‐assisted ligand incorporation (SALI) approach. SALI‐MOFs were characterized by various technique including powder X‐ray diffraction, scanning electron microscope, N 2 adsorption/desorption isotherms, Fourier transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The SALI‐MOFs were found to have cooperative light‐harvesting properties and shown to possess efficient singlet oxygen ( 1 O 2 ) generation ability.