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Remarkable Solvent Effects of Structurally Diverse Alcohols on Nucleophilic Displacement Reactions with Halide Ions
Author(s) -
Moon Byung Seok,
Lee Byoung Se,
Chu So Young,
Kim Dong Wook,
Chi Dae Yoon
Publication year - 2018
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.11496
Subject(s) - halide , nucleophile , chemistry , solvent , alcohol , solvent effects , ion , alkyl , nucleophilic substitution , halogen , photochemistry , organic chemistry , inorganic chemistry , catalysis
Solvent effects on nucleophilic displacement reactions of alkyl mesylates with halide ions were investigated in a series of protic alcohol solvents. In consideration of Hughes and Ingold's principle, the reaction rates were found to correlate well with the normalized solvent polarities ( E T N ) in all halide reactions.