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Electrochemical Study of Ferrocene and Anthracene using Ultramicroelectrode in Chloroform over the Temperature Range of 25–50°C
Author(s) -
Nguyen Truc Ly,
Lee Eui Joo,
Jeong Hyuk,
Kim ByungKwon
Publication year - 2017
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.11169
Subject(s) - anthracene , ultramicroelectrode , chloroform , ferrocene , chemistry , cyclic voltammetry , electrochemistry , perchlorate , analytical chemistry (journal) , voltammetry , inorganic chemistry , chromatography , organic chemistry , electrode , ion
In this study, electrochemical experiments were carried out in chloroform using ferrocene (Fc) or anthracene (An). We performed cyclic voltammetry ( CV ) on Fc and An in chloroform containing either tetrabutylammonium perchlorate ( TBAP ) or tetrabutylammonium hexafluoro‐phosphate ( TBAPF 6 ) over the temperature range of 25 to 50°C. The resulting pattern of CVs , half‐wave potential ( E 1 /2 ), diffusion coefficient of Fc and An, steady‐state current, solution viscosity, and long‐term stabilities were studied.