z-logo
Premium
Efficient Removal of Bisphenol A by an Advanced Photocatalytic Oxidation‐type UV / H 2 O 2 /Fe‐loaded TiO 2 System
Author(s) -
Kang Sora,
Do Jeong Yeon,
Jo Seung Won,
Kim Kang Min,
Jeong Kyung Mi,
Park SunMin,
Kang Misook
Publication year - 2015
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.10387
Subject(s) - photocatalysis , bisphenol a , catalysis , photoluminescence , degradation (telecommunications) , materials science , photochemistry , visible spectrum , nuclear chemistry , irradiation , chemistry , organic chemistry , composite material , optoelectronics , physics , nuclear physics , telecommunications , computer science , epoxy
This study focuses on the photocatalytic degradation efficiency of bisphenol A ( BPA ) when H 2 O 2 is used. Based on the Fenton oxidation reaction, Fe ions (3.0, 5.0, and 10.0 mol%) loaded on the external surface of TiO 2 nano‐sized materials as a photocatalyst were synthesized using a common solvothermal/impregnation hybrid method. With increasing Fe ion loading, the light absorption shifted to a longer wavelength, indicating shorter bandgaps, and the photoluminescence ( PL) intensities decreased dramatically. The photocatalytic activities of two systems, namely a UV /photocatalytic system and an advanced photocatalytic oxidation‐type UV / H 2 O 2 /photocatalytic system, were compared using two types of catalysts, TiO 2 and Fe‐ TiO 2 . Slightly more BPA molecules decomposed in the UV / TiO 2 photocatalytic system than the UV /Fe‐ TiO 2 system. On the other hand, the level of BPA destruction was significantly higher in the UV / H 2 O 2 /Fe‐ TiO 2 system. In particular, BPA molecules at 10.0 ppm were removed completely after only 2 h in the UV / H 2 O 2 /5.0 mol% Fe‐ TiO 2 photocatalytic system. These results confirm that the added H 2 O 2 promotes the BPA oxidation on the Fe‐loaded TiO 2 catalytic system.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom