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Synthesis and Characterization of Rhodium(I) Complexes with P–N Donor Ligands and Their Catalytic Application in Transfer Hydrogenation of Carbonyl Group
Author(s) -
Borah Geetika,
Sarmah Podma Pollov,
Boruah Devajani
Publication year - 2015
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.10237
Subject(s) - chemistry , rhodium , catalysis , pyridine , transfer hydrogenation , medicinal chemistry , molar ratio , melting point , mass spectrometry , carbonyl group , organic chemistry , ruthenium , chromatography
Synthesis and characterization of three neutral complexes of Rh(I) with 2‐[2‐(diphenylphosphino) ethyl]pyridine, ( PPh 2 Etpy ) ( a ), 2‐(diphenylphosphino)pyridine ( PPh 2 py ) ( b ), and 3‐(diphenylphosphino)‐1‐propylamine ( PPh 2 ( CH 2 ) 3 NH 2 ) ( c ) are reported. These complexes exhibit good catalytic activity toward the transfer hydrogenation of carbonyl compounds to the corresponding alcohols with high conversion rate.