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Synthesis of Pyrazolo[1,5‐ a ]quinolines from 1‐Aryl‐5‐styrylpyrazoles via Intramolecular Friedel‐Crafts Reaction/Aerobic Oxidation
Author(s) -
Moon Hye Ran,
Yu Jin,
Kim Ko Hoon,
Kim Jae Nyoung
Publication year - 2015
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.10225
Subject(s) - intramolecular force , friedel–crafts reaction , aryl , chemistry , oxidation process , conjugated system , base (topology) , catalysis , combinatorial chemistry , organic chemistry , medicinal chemistry , polymer , chemical engineering , alkyl , mathematical analysis , mathematics , engineering
Various pyrazolo[1,5‐ a ]quinolines were synthesized via the intramolecular Friedel‐Crafts reaction of 1‐aryl‐5‐styrylpyrazoles and the following base‐catalyzed aerobic oxidation process. The required 1‐aryl‐5‐styrylpyrazoles were readily prepared from the corresponding conjugated dienones and arylhydrazines in a one‐pot process.

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