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Palladium( II ) Complexes with N,N′ ‐Bidentate N ‐Methyl‐ N ‐(pyridin‐2‐ylmethyl)aniline and its Derivatives: Synthesis, Characterization, and Methyl Methacrylate Polymerization
Author(s) -
Kim Sunghoon,
Song Yujin,
Lee HaJin,
Jeon Jongho,
Park Sang Hyun,
Lee Hyosun
Publication year - 2015
Publication title -
bulletin of the korean chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.237
H-Index - 59
ISSN - 1229-5949
DOI - 10.1002/bkcs.10119
Subject(s) - methylaluminoxane , denticity , chemistry , aniline , palladium , methyl methacrylate , polymerization , medicinal chemistry , catalysis , organometallic chemistry , polymer chemistry , crystallography , crystal structure , metallocene , organic chemistry , polymer
The N ‐methyl‐ N ‐(pyridin‐2‐ylmethyl)aniline and its derivatives containing square‐planar palladium(II) complexes, [L n PdCl 2 ] (L n = L 1 –L 5 ), were structurally characterized. The catalytic activity of Pd(II) complexes toward the methyl methacrylate (MMA) polymerization in the presence of modified methylaluminoxane (MMAO) was compared to that of the corresponding reference Pd(II) complex, [PdCl 2 ] , at 60 °C.