Premium
Influence of oxygen adsorption on the dynamic K L a measurement in three‐phase slurry reactors
Author(s) -
Boon M.,
Meeder T. A.,
Heijnen J. J.,
Luyben K. Ch. A. M.
Publication year - 1992
Publication title -
biotechnology and bioengineering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.136
H-Index - 189
eISSN - 1097-0290
pISSN - 0006-3592
DOI - 10.1002/bit.260400914
Subject(s) - slurry , mass transfer , coal slurry , chemistry , mass transfer coefficient , adsorption , oxygen , carbon dioxide , carbon fibers , coal , analytical chemistry (journal) , phase (matter) , absorption (acoustics) , continuous stirred tank reactor , thermodynamics , chromatography , materials science , organic chemistry , physics , composite number , composite material
To check for possible mass transfer limitations of oxygen and/or carbon dioxide in kinetic experiments on microbial desulphurization of coal, it is important to properly measure the volumetric mass transfer coefficient ( k L a ) especially at high slurry densities. Volumetric mass transfer coefficients of oxygen, at different solid hold‐up values (ε s = 0 to 0.28) of coal slurries ( d par < 100 * 10 −6 m), were measured in a lab scale fermentor and in a lab scale pachuca tank, using the dynamic gas–liquid absorption method. It was shown that serious errors could occur due to oxygen adsorption at the coal surface. Using the data of an independently measured adsorption isotherm, the real k L a could be calculated from the measured apparent k L a . The results show a k L a decrease of 40% to 50% at a volumetric solid hold‐up of 28%. Estimation of the oxygen and carbon dioxide transfer rates, from the measured mass transfer coefficients, indicates that the stirred fermentor is suitable for kinetic experiments at high slurry densities, whereas the pachuca tank and shake flask are not. © 1992 John Wiley & Sons, Inc.