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Binding of alcohols to the peptide CO‐group of poly‐ L ‐proline in the I and II conformation. I. Demonstration of the binding by infrared spectroscopy and optical rotatory dispersion
Author(s) -
Strassmair H.,
Engel J.,
Zundel G.
Publication year - 1969
Publication title -
biopolymers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.556
H-Index - 125
eISSN - 1097-0282
pISSN - 0006-3525
DOI - 10.1002/bip.1969.360080209
Subject(s) - polyproline helix , chemistry , optical rotatory dispersion , hydrogen bond , alcohol , peptide , infrared spectroscopy , spectroscopy , ring (chemistry) , crystallography , stereochemistry , benzyl alcohol , dispersion (optics) , butanol , infrared , circular dichroism , photochemistry , ethanol , organic chemistry , molecule , catalysis , biochemistry , physics , quantum mechanics , optics
The binding of n ‐butanol, benzyl alcohol, and trifluoroethanol to polyproline I (all peptide bonds in cis configuration) and II (all peptide bonds in trans configuration) has been demonstrated. It was found by infrared spectroscopy that hydrogen bonds are formed between the CO groups of the polymer and the OH groups of the alcohols. Their strength increases from n ‐butanol via benzyl alcohol to trifluoroethanol. The binding of benzyl alcohol could also be followed by optical rotatory dispersion due to the fact that the electronic transitions of the benzyl ring are rendered optically active by the binding to the polymer.