Enthalpy change of the coil–helix transition of poly(γ‐benzyl  L ‐glutamate) in dichloroacetic acid–1,2‐dichloroethane mixtures | Zendy

Kagemoto Akihiro | Zendy; Fujishiro Ryoichi | Zendy

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Enthalpy change of the coil–helix transition of poly(γ‐benzyl L ‐glutamate) in dichloroacetic acid–1,2‐dichloroethane mixtures

Author(s) -

Kagemoto Akihiro,

Fujishiro Ryoichi

Publication year - 1968

Publication title -

biopolymers

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.556

H-Index - 125

eISSN - 1097-0282

pISSN - 0006-3525

DOI - 10.1002/bip.1968.360061210

Subject(s) - dichloroacetic acid , chemistry , 1,2 dichloroethane , enthalpy , dilution , helix (gastropod) , thermodynamics , electromagnetic coil , organic chemistry , physics , ecology , biology , snail , catalysis , quantum mechanics

By combining the heat of dilution of a poly(γ‐benzyl L ‐glutamate)–dichloroacetic acid–1, 2‐dichloroethane solution with the corresponding heat of mixing of two solvents, the integrated heat of the coil–helix transition of poly(γ‐benzyl L ‐glutamate) in the solution was estimated to be about 750 cal/mole.

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