Studies on PVP hydrogel‐supported luminol chemiluminescence: 1. Kinetic and mechanistic aspects using multivariate factorial analysis | Zendy

Bastos Erick Leite | Zendy; Ciscato Luiz Francisco Monteiro Leite | Zendy; Bartoloni Fernando Heering | Zendy; Catalani Luiz Henrique | Zendy; Baader Wilhelm Josef | Zendy

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Studies on PVP hydrogel‐supported luminol chemiluminescence: 1. Kinetic and mechanistic aspects using multivariate factorial analysis

Author(s) -

Bastos Erick Leite,

Ciscato Luiz Francisco Monteiro Leite,

Bartoloni Fernando Heering,

Catalani Luiz Henrique,

Baader Wilhelm Josef

Publication year - 2006

Publication title -

luminescence

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.428

H-Index - 45

eISSN - 1522-7243

pISSN - 1522-7235

DOI - 10.1002/bio.934

Subject(s) - chemiluminescence , luminol , chemistry , multivariate statistics , luminescent measurements , factorial experiment , kinetic energy , factorial analysis , chromatography , luminescence , materials science , mathematics , statistics , optoelectronics , physics , quantum mechanics

The chemiluminescent oxidation of luminol by hydrogen peroxide in the presence of hemin is revisited in an UV‐C cross‐linked PVP hydrogel. Chemiluminescence properties such as initial light intensity ( I 0 ), area of emission ( S ) and observed rate constants ( k obs ) are studied, varying the concentration of all reactants using a multivariate factorial approach. Copyright © 2006 John Wiley & Sons, Ltd.

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