The fluorescence sensor for saccharide based on internal conversion | Zendy

Sun XiangYing | Zendy; Liu Bin | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

The fluorescence sensor for saccharide based on internal conversion

Author(s) -

Sun XiangYing,

Liu Bin

Publication year - 2005

Publication title -

luminescence

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.428

H-Index - 45

eISSN - 1522-7243

pISSN - 1522-7235

DOI - 10.1002/bio.841

Subject(s) - chemistry , fluorescence , fructose , quantum yield , boronic acid , yield (engineering) , solvent , buffer solution , photochemistry , chromatography , organic chemistry , materials science , physics , quantum mechanics , metallurgy

In this paper, an internal conversion (IC) fluorescence probe N‐( o ‐boronic acid)benzyl‐1‐naphthylamine (BBNA) was prepared from 1‐naphthylamine and 2‐formylbenzeneboronic acid. The fluorescence parameters of BBNA were investigated in a variety of solvents. When BBNA interacted with d ‐fructose in phosphate buffer solution of 30% MeOH, pH 8.21 (v/v), the fluorescence intensity increased and emission maximum red‐shifted slightly with increasing d ‐fructose concentration. In the presence of d ‐fructose, the fluorescence quantum yield of BBNA increased with increasing solvent polarity, suggesting that internal conversion (IC) occurred with BBNA. The binding force of BBNA with d ‐fructose was the strongest, and the stability constant ( K ) of d ‐fructose was 99.9 mol/L. Therefore, a selective recognition system based on IC was constructed for d ‐fructose. Copyright © 2005 John Wiley & Sons, Ltd.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research