Premium
Novel enantioselective fluorescent sensors for tartrate anion based on acridinezswsxa
Author(s) -
Wang Chaoyu,
Wang Peng,
Liu Xiaoyan,
Fu Jiaxin,
Xue Kun,
Xu Kuoxi
Publication year - 2017
Publication title -
luminescence
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.428
H-Index - 45
eISSN - 1522-7243
pISSN - 1522-7235
DOI - 10.1002/bio.3327
Subject(s) - tartrate , fluorescence , enantioselective synthesis , titration , carboxylate , chemistry , hydrogen bond , enantiomer , ion , density functional theory , fluorescence spectroscopy , molecule , stereochemistry , inorganic chemistry , organic chemistry , computational chemistry , catalysis , physics , quantum mechanics
Novel chiral fluorescence sensors L‐1 and D‐1 incorporating N ‐Boc‐protected alanine and acridine moieties were synthesized. The recognition ability of the sensors was studied by fluorescence titration, 1 H NMR spectroscopy and density functional theory (DFT) calculations. The sensors exhibited good enantioselective fluorescent sensing ability toward enantiomers of tartrate anion for the selected carboxylate anions and formed 1: 1 complexes by multiple hydrogen bonding interactions.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom