Pyrolytic synthesis and luminescence of porous lanthanide Eu‐MOF | Zendy

Jin Guangya | Zendy; Liu Zhijian | Zendy; Sun Hongfa | Zendy; Tian Zhiyong | Zendy

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Pyrolytic synthesis and luminescence of porous lanthanide Eu‐MOF

Author(s) -

Jin Guangya,

Liu Zhijian,

Sun Hongfa,

Tian Zhiyong

Publication year - 2016

Publication title -

luminescence

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.428

H-Index - 45

eISSN - 1522-7243

pISSN - 1522-7235

DOI - 10.1002/bio.2944

Subject(s) - lanthanide , luminescence , europium , hydrothermal synthesis , dimethyl sulfoxide , gravimetric analysis , powder diffraction , chemistry , hydrothermal circulation , pyrolytic carbon , inorganic chemistry , nuclear chemistry , materials science , crystal structure , crystallography , organic chemistry , chemical engineering , pyrolysis , ion , optoelectronics , engineering

A lanthanide metal coordination polymer [Eu 2 (BDC) 3 (DMSO)(H 2 O)] was synthesized by the reaction of europium oxide with benzene‐1,3‐dicarboxylic acid (H 2 BDC) in a mixed solution of dimethyl sulfoxide (DMSO) and water under hydrothermal conditions. The crystal structure of Eu 2 (BDC) 3 (DMSO)(H 2 O) was characterized by X‐ray diffraction (XRD). Thermo‐gravimetric analysis of Eu 2 (BDC) 3 (DMSO)(H 2 O) indicated that coordinated DMSO and H 2 O molecules could be removed to create Eu 2 (BDC) 3 (DMSO)(H 2 O)‐py with permanent microporosity, which was also verified by powder XRD (PXRD) and elemental analysis. Both Eu 2 (BDC) 3 (DMSO)(H 2 O) and Eu 2 (BDC) 3 (DMSO)(H 2 O)‐py showed mainly Eu‐based luminescence and had characteristic emissions in the range 550–700 nm. Copyright © 2015 John Wiley & Sons, Ltd.

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