Synthesis of some novel quinone diimine derivatives of benzo‐15‐crown‐5 for application in Hg 2+  recognition | Zendy

Jagadale S. D. | Zendy; Sawant A. D. | Zendy; Patil P. P. | Zendy; Patil D. R. | Zendy; Mulik A. G. | Zendy; Chandam D. R. | Zendy; Sankpal S. A. | Zendy; Deshmukh M. B. | Zendy

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Synthesis of some novel quinone diimine derivatives of benzo‐15‐crown‐5 for application in Hg 2+ recognition

Author(s) -

Jagadale S. D.,

Sawant A. D.,

Patil P. P.,

Patil D. R.,

Mulik A. G.,

Chandam D. R.,

Sankpal S. A.,

Deshmukh M. B.

Publication year - 2014

Publication title -

luminescence

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.428

H-Index - 45

eISSN - 1522-7243

pISSN - 1522-7235

DOI - 10.1002/bio.2585

Subject(s) - quinone , chemistry , diimine , stereochemistry , organic chemistry , catalysis

A series of novel fluoroionophore bearing derivatives of benzo‐15‐crown‐5 were synthesized by the amination of benzo‐15‐crown‐5 followed by condensation with different quinones in the presence of titanium tetrachloride (TiCl 4 ) and 1,4‐diazabicyclo‐[2.2.2]octane. The compounds were characterized by infrared, 1 H and 13 C nuclear magnetic resonance, mass spectroscopy and elemental analysis. Absorption and fluorescence spectral characteristics of these compounds were studied. It was observed that the anthraquinone derivative was acting as an Hg 2+ ion sensor. Copyright © 2013 John Wiley & Sons, Ltd.

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