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Sensitive and selective system of benzene detection based on a cataluminescence sensor
Author(s) -
Li Bo,
Zhang Yuejin,
Liu Juefu,
Xie Xin,
Zou Dan,
Li Minqiang,
Liu Jinhuai
Publication year - 2014
Publication title -
luminescence
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.428
H-Index - 45
eISSN - 1522-7243
pISSN - 1522-7235
DOI - 10.1002/bio.2548
Subject(s) - chemistry , benzene , organic chemistry
Au/La 2 O 3 nanomaterials were prepared through calcining Au‐modified La(OH) 3 precursors. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X‐ray diffractometry (XRD) were employed to characterize the as‐prepared samples. Benzene, a common volatile organic compound, was selected as a model to investigate the cataluminescence (CTL)‐sensing properties of the Au/La 2 O 3 nanomaterials. Results indicated that the as‐prepared Au/La 2 O 3 exhibited outstanding CTL properties such as stable intensity, high signal‐to‐noise values, and short response and recovery times. Under optimized conditions, the benzene assay exhibited a broad linear range of 1–4000 ppm, with a limit of detection of 0.7 ppm, which was below the standard permitted concentrations. Furthermore, the gas sensor system showed outstanding selectivity for benzene compared with seven other types of common volatile organic compounds (VOCs). The proposed gas sensor showed good characteristics with high selectivity, fast response time and long lifetime, which suggested the promising application of the Au/La 2 O 3 nanomaterials as a novel highly efficient CTL‐sensing material. Copyright © 2013 John Wiley & Sons, Ltd.