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The configuration, solvatochromism and metallo‐responses of two novel cyano‐containing oligo(phenylene‐vinylene) derivatives
Author(s) -
Lv Jing,
Yin Xiaodong,
Zheng Haiyan,
Li Yongjun,
Li Yuliang,
Zhu Daoben
Publication year - 2011
Publication title -
luminescence
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.428
H-Index - 45
eISSN - 1522-7243
pISSN - 1522-7235
DOI - 10.1002/bio.1204
Subject(s) - solvatochromism , intramolecular force , phenylene , alkyl , chemistry , photochemistry , polymer chemistry , core (optical fiber) , combinatorial chemistry , materials science , stereochemistry , molecule , organic chemistry , polymer , composite material
Two novel cyano‐containing oligo(phenylenevinylene) (OPV) derivatives have been designed and synthesized. Photophysical and sensing properties of the two compounds were studied. Such studies reveal the intramolecular charge transfer process between cyano groups and OPV core. The results showed that the alkyl difference of substituted OPV leads to the changes of molecular configuration and metallo‐response of two compounds. Copyright © 2010 John Wiley & Sons, Ltd.