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Sodium‐Ion Battery Full‐Cell Study with a Pseudocapacitive MoSe 2 ‐Porous N‐Doped Carbon Composite Anode and Intercalated Sodium Vanadium Fluorophosphate Cathode
Author(s) -
Roy Amlan,
Sarkar Ananta,
Adil Md.,
Sau Supriya,
Abhara.,
Mitra Sagar
Publication year - 2021
Publication title -
batteries and supercaps
Language(s) - English
Resource type - Journals
ISSN - 2566-6223
DOI - 10.1002/batt.202100026
Subject(s) - materials science , anode , sodium ion battery , electrolyte , chemical engineering , graphene , cathode , x ray photoelectron spectroscopy , composite number , graphite , nanotechnology , composite material , electrode , chemistry , faraday efficiency , engineering
Despite higher conductivity and larger d‐spacing (0.65 nm) of MoSe 2 compare to its analogous MoS 2 and higher theoretical capacity (∼422 mA h g −1 ) compare to commercially available graphite, it experiences high volume expansion, sheets agglomeration during cycling, which limits their capacities and high rate application. Herein, we have shown interest in MoSe 2 materials as analogous to MoS 2 anode and grown MoSe 2 nanosheets on the nitrogen‐doped carbon followed by covered with reduced graphene oxides sheets (NC@MoSe 2 @rGO) composite through a simple solvothermal synthesis followed by annealing treatment. The porous NC compound could bring several advantages like, it can reserve a sufficient amount of electrolyte for easy access of Na‐ion diffusion. Increasing the conductivity by introducing the doping of nitrogen on the NC structure and simultaneously rGO can reduce the volume expansion of MoSe 2 during the cyclic performance. Ex‐situ XANES and XPS technique explored the sodiation mechanism of the NC@MoSe 2 @rGO composite. It has been found the irreversible conversion of MoSe 2 after 1 st cycle by converting the discharged products of Mo and Na 2 Se. The NC@MoSe 2 @rGO anode is connected with electrolyte and a high potential Na 3 V 2 O 2 (PO 4 ) 2 F (NVOPF) to acquire potential applications′ approval cathode material. The full‐cell delivers a voltage of operation at 2.1 V with high specific capacity of ∼176 mA h g −1 (current rate of 0.05 A g −1 ) with an energy density of ∼369.6 W h/kg anode at 20 °C.