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Amine‐ and Amide‐Functionalized Mesoporous Carbons: A Strategy for Improving Sulfur/Host Interactions in Li–S Batteries
Author(s) -
Fretz Samuel J.,
Agostini Marco,
Jankowski Piotr,
Johansson Patrik,
Matic Aleksandar,
Palmqvist Anders E. C.
Publication year - 2020
Publication title -
batteries and supercaps
Language(s) - English
Resource type - Journals
ISSN - 2566-6223
DOI - 10.1002/batt.202000027
Subject(s) - sulfur , amine gas treating , electrochemistry , nucleophile , mesoporous material , amide , carbon fibers , chemistry , lithium (medication) , cathode , surface modification , sulfide , lithium–sulfur battery , inorganic chemistry , chemical engineering , materials science , organic chemistry , electrode , catalysis , composite material , medicine , composite number , engineering , endocrinology
Lithium–sulfur (Li–S) batteries are of great interest due to their potentially high energy density, but the low electronic conductivity of both the sulfur (S 8 ) cathode active material and the final discharge product lithium sulfide (Li 2 S) require the use of a conductive host. Usually made of relatively hydrophobic carbon, such hosts are typically ill‐suited to retain polar discharge products such as the intermediate lithium polysulfides (LiPs) and the final Li 2 S. Herein, we propose a route to increase the sulfur utilization by functionalizing the surface of ordered mesoporous carbon CMK3 with polar groups. These derivatized CMK3 materials are made using a simple two‐step procedure of bromomethylation and subsequent nucleophilic substitution with amine or amide nucleophiles. We demonstrate that, compared to the unfunctionalized control, these modified CMK3 surfaces have considerably larger binding energies with LiPs and Li 2 S, which are proposed to aid the electrochemical conversion between S 8 and Li 2 S by keeping the LiPs species in close proximity to the carbon surface during Li–S battery cycling. As a result, the functionalized cathodes exhibit significantly improved specific capacities relative to their unmodified precursor.