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Sulfur‐Doped Carbon‐Wrapped Heterogeneous Fe 3 O 4 /Fe 7 S 8 /C Nanoplates as Stable Anode for Lithium‐Ion Batteries
Author(s) -
Chen Kang,
Kong Xiangzhong,
Xie Xuefang,
Chen Jing,
Cao Xinxin,
Liang Shuquan,
Pan Anqiang
Publication year - 2020
Publication title -
batteries and supercaps
Language(s) - English
Resource type - Journals
ISSN - 2566-6223
DOI - 10.1002/batt.201900134
Subject(s) - materials science , sulfidation , anode , lithium (medication) , bimetallic strip , chemical engineering , composite number , sulfide , electrode , carbon fibers , diffusion , metal , sulfur , metallurgy , composite material , chemistry , medicine , endocrinology , physics , engineering , thermodynamics
High‐capacity electrode materials have attracted tremendous attention in energy storage systems. However, the large volume expansion always causes breakdown of electrode materials and capacity fading. In this work, we report the preparation of heterogeneous Fe 3 O 4 /Fe 7 S 8 /C nanoplates with a high lithium diffusion coefficient and excellent lithium storage performance. The heterogeneous nanoplates can be derived from Fe‐MOF octahedra during the sulfidation process. As an anode for lithium‐ion batteries, the Fe 3 O 4 /Fe 7 S 8 /C composite exhibits higher specific capacity and better rate capability than Fe 3 O 4 /C and Fe 7 S 8 /C counterparts. The Fe 3 O 4 /Fe 7 S 8 /C nanoplates deliver a reversible capacity of 859 mA h g −1 after 100 cycles at 0.1 A g −1 . Even at 2 A g −1 , a capacity of 549 mA h g −1 can still be remained. The good performances are attributed to the small nanocrystallites, high surface area, and the heterogeneous phase boundaries. The strategy can be potentially applied to other metal oxide/metal sulfide composite phases or even bimetallic sulfides and bimetal oxides for high performance lithium‐ion batteries.