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Elemental Sulfur Nanoparticles Chemically Boost the Sodium Storage Performance of MoS 2 /rGO Anodes
Author(s) -
Xu Zhanwei,
Fu Hao,
Yao Kai,
Shen Xuetao,
Li Zhi,
Fu Licai,
Huang Jianfeng,
Li Jiayin
Publication year - 2018
Publication title -
batteries and supercaps
Language(s) - English
Resource type - Journals
ISSN - 2566-6223
DOI - 10.1002/batt.201800060
Subject(s) - sulfur , graphene , anode , nanoparticle , oxide , materials science , chemical engineering , sodium molybdate , chemical vapor deposition , intercalation (chemistry) , molybdate , inorganic chemistry , nanotechnology , chemistry , electrode , metallurgy , engineering
The critical role of sulfur nanoparticles in stabilizing MoS 2 supported on reduced graphene oxide as anode material for sodium‐ion batteries is discovered. The MoS 2 supported on reduced graphene oxide decorated with sulfur particles (∼50 nm) is in‐situ synthesized using an ammonium molybdate/graphene oxide preform and sublimed sulfur through a facile chemical vapor deposition process in a tube furnace with 2 temperature‐controlled zones. Although the sulfur particles show no positive effect when the material is tested as anode for Li‐ion batteries, they significantly improve the Na storage performance in terms of both, total specific capacity and cycle life. A stable high capacity of 580 mAh g −1 and an extremely low capacity fade of 94 μAh g −1 cycle −1 make the designed assembly one of the best‐performing MoS 2 ‐based anode materials for sodium‐ion batteries so far. The post‐cycling analysis reveals that the elemental sulfur nanoparticles play two roles: during the intercalation of Na in‐between the layers of MoS 2 (above 1.0 V), they function as blockers and inhibit the aggregation of MoS 2 ; in the conversion reaction stage, the sulfur nanoparticles chemically participate in the Na storage process by forming Na 2 S 5 ‐rich compounds, which eventually improve the reversibility of the conversion reaction and thereafter the cycling performance.