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Synthesis and Pyrolysis of Fullerenol‐stabilized Pt Nanocolloids as a unique Approach to Pt‐doped Carbon
Author(s) -
Cabello Mark Kristan Espejo,
Uetake Yuta,
Yao Yu,
Kuwabata Susumu,
Sakurai Hidehiro
Publication year - 2021
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.202100495
Subject(s) - pyrolysis , cyclic voltammetry , linear sweep voltammetry , materials science , thermogravimetric analysis , nanocomposite , carbon fibers , x ray absorption spectroscopy , aqueous solution , catalysis , infrared spectroscopy , absorption spectroscopy , nuclear chemistry , electrochemistry , inorganic chemistry , chemistry , organic chemistry , nanotechnology , composite number , electrode , composite material , physics , quantum mechanics
An aqueous colloidal dispersion of Pt nanoparticles (NPs) stabilized by fullerenol C 60 (OH) 12 (Pt:C 60 (OH) 12 ) was successfully synthesized via liquid‐phase chemical reduction. The subsequent pyrolysis of Pt:C 60 (OH) 12 at different temperatures was conducted to afford Pt‐doped carbon with different chemical compositions (Pt:C60 n ). X‐ray absorption spectroscopy (XAS) and Infrared (IR) absorption spectroscopy and thermogravimetric measurements revealed that the thus‐prepared nanocomposite consists of Pt NPs and high valent Pt‐C 60 (OH) 12 complex. One distinct feature of C 60 (OH) 12 matrix as catalyst support is the suppression of size growth of Pt NPs during the pyrolysis up to 300 °C. Electrochemical experiments using cyclic voltammetry (CV) and linear sweep voltammetry (LSV) were performed to find that Pt:C60 300 (pyrolyzed at 300 °C) exhibited higher activity than others, that was attributed to the π‐extended feature of the as‐obtained carbon.