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Selective Photocatalytic Oxidation of Sulfides in Lanthanide Metal ‐Organic Frameworks Incorporating Ru(2,2′‐bpy) 3 photosensitizer
Author(s) -
Zhang Xiaobang,
Wei Xiaomei,
Huang ShengLi,
Yang GuoYu
Publication year - 2021
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.202100482
Subject(s) - isostructural , lanthanide , photosensitizer , photocatalysis , metal organic framework , chemistry , metal , selectivity , sulfoxide , photochemistry , catalysis , bifunctional , inorganic chemistry , organic chemistry , crystal structure , ion , adsorption
Three isostructural lanthanide metal‐organic frameworks (Ln‐MOFs) were synthesized with uncoordinated N^N site, and the Ru(N^N) 3 photosensitizer was introduced via coordination link. These functionalized frameworks showed excellent performance in the photocatalytic oxidation of sulfides with good conversion and high sulfoxide selectivity.