Palladium/Zinc Co‐Catalyzed Asymmetric Hydrogenation of γ‐Keto Carboxylic Acids | Zendy

Zhang Keyang | Zendy; Zhang Xuexin | Zendy; Chen Jingchao | Zendy; Liu Zixiu | Zendy; Pan Chunxiang | Zendy; Zhu Yuanbin | Zendy; Wu Shiyuan | Zendy; Fan Baomin | Zendy

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Palladium/Zinc Co‐Catalyzed Asymmetric Hydrogenation of γ‐Keto Carboxylic Acids

Author(s) -

Zhang Keyang,

Zhang Xuexin,

Chen Jingchao,

Liu Zixiu,

Pan Chunxiang,

Zhu Yuanbin,

Wu Shiyuan,

Fan Baomin

Publication year - 2021

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.202100244

Subject(s) - palladium , catalysis , levulinic acid , ketone , chemistry , zinc , asymmetric hydrogenation , carboxylic acid , organic chemistry , noyori asymmetric hydrogenation , enantioselective synthesis

A palladium‐catalyzed asymmetric hydrogenation of levulinic acid has been successful developed by using Zn(OTf) 2 as co‐catalyst. The present method not only has provided a strategy in the palladium‐catalyzed asymmetric hydrogenation of ketone, but also allowed the preparation of a wide range of chiral γ‐valerolactones in good yields with excellent enantioselectivities.

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