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Blue Light‐promoted Carbene Transfer Reactions of Tosylhydrazones
Author(s) -
Xu Yingying,
Lv Guanghui,
Yan Kaichuan,
He Hua,
Li Jianglian,
Luo Yi,
Lai Ruizhi,
Hai Li,
Wu Yong
Publication year - 2020
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.202000378
Subject(s) - carbene , photochemistry , chemistry , irradiation , polymer chemistry , organic chemistry , catalysis , physics , nuclear physics
Metal‐free photochemical carbene‐transfer reactions of tosylhydrazones were developed under blue light irradiation at room temperature. This reaction constructs C−X (X=C, N, O, S) bonds and cyclopropanes from readily available and stable starting materials.