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Zinc‐catalyzed transformation of diarylphosphoryl azides to diarylphosphate esters and amides
Author(s) -
Ying Jun,
Gao Qian,
Wu XiaoFeng
Publication year - 2020
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.202000154
Subject(s) - catalysis , chemistry , phenols , organic chemistry , zinc , cleavage (geology) , bond cleavage , reaction conditions , transformation (genetics) , combinatorial chemistry , materials science , biochemistry , fracture (geology) , composite material , gene
We have developed a facile and efficient procedure for the synthesis of diarylphosphate esters and amides. Using Zn(acac) 2 as the catalyst, the reaction of diarylphosphoryl azides with aliphatic alcohols and phenols through an unusual P−N bond cleavage provided a number of diarylphosphate esters in good yields (22 examples, up to 94%). Additionally, various diarylphosphate amides were obtained from the corresponding amines in excellent yields as well (8 examples, up to 96%).
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