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Catalytic Carbonylation and Carboxylation of Organosulfur Compounds via C−S Cleavage
Author(s) -
Nogi Keisuke,
Yorimitsu Hideki
Publication year - 2020
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201901644
Subject(s) - organosulfur compounds , carbonylation , carboxylation , chemistry , catalysis , halide , organic chemistry , organic synthesis , catalytic cycle , combinatorial chemistry , carbon monoxide , sulfur
Transition‐metal‐catalyzed carbonylation with CO gas occupies a privileged position in organic synthesis for the synthesis of carbonyl compounds. Although this attractive and useful chemistry has led many researchers to investigate carbonylative transformations of various organic (pseudo)halides, C−S‐cleaving carbonylation of organosulfur compounds has been fairly limited. Recently, a broad spectrum of C−S‐cleaving transformations has been emerging in the field of cross‐coupling. In light of the importance of carbonyl compounds as well as considerable advancement for employing organosulfur compounds as competent surrogates of (pseudo)halides, carbonylative transformations of C−S bonds should be of high value. This Minireview focuses on catalytic C−S carbonylation of organosulfur compounds with CO or its equivalents. In addition, reductive carboxylation of C−S bonds with CO 2 is described.