A Temperature‐Sensitive Luminescent Ag 42  Nanocluster Supported by  Tert Butyl Thiol Ligands | Zendy

Feng YuHui | Zendy; Gao XiangLing | Zendy; Shi JuFeng | Zendy; Zhou Kun | Zendy; Ji JiuYu | Zendy; Bi YanFeng | Zendy

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A Temperature‐Sensitive Luminescent Ag 42 Nanocluster Supported by Tert Butyl Thiol Ligands

Author(s) -

Feng YuHui,

Gao XiangLing,

Shi JuFeng,

Zhou Kun,

Ji JiuYu,

Bi YanFeng

Publication year - 2019

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201901146

Subject(s) - thiol , luminescence , chemistry , materials science , nanotechnology , organic chemistry , optoelectronics

Compound [Ag 42 S 5 (S t Bu) 25 (CF 3 COO) 4 (CO 3 )](CO 3 ) 0.5 ⋅CH 2 Cl 2 ⋅4CH 3 OH⋅9DMF ( 1 ) has been obtained and well defined. It consists of a multi‐shell structure involving two Ag centres, one Ag 5 S 5 pentagram, two Ag 5 S 5 pentagons and one Ag 25 S 15 shell. Compound 1 has been characterized by XPS, FT‐IR, PXRD, TGA, NMR, MS, UV/Vis spectrum, TEM and cyclic voltammetry. Temperature‐sensitive luminescent property of 1 has also been investigated.

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