Zn‐ and Cd‐based Coordination Polymers Offering H‐Bonding Cavities: Highly Selective Sensing of S 2 O 7  2−  and Fe 3+  Ions | Zendy

Kumar Gulshan | Zendy; Pachisia Sanya | Zendy; Kumar Pramod | Zendy; Kumar Vijay | Zendy; Gupta Rajeev | Zendy

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Zn‐ and Cd‐based Coordination Polymers Offering H‐Bonding Cavities: Highly Selective Sensing of S 2 O 7 2− and Fe 3+ Ions

Author(s) -

Kumar Gulshan,

Pachisia Sanya,

Kumar Pramod,

Kumar Vijay,

Gupta Rajeev

Publication year - 2019

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201901142

Subject(s) - ion , fluorescence , quenching (fluorescence) , polymer , chemistry , crystallography , coordination polymer , materials science , analytical chemistry (journal) , inorganic chemistry , physics , organic chemistry , quantum mechanics

We present two Zn II ‐ and Cd II ‐based coordination polymers (CPs), L ‐Zn and L ‐Cd , offering H‐bonding‐based cavities of varying dimensions. Both CPs were used for the highly selective detection of S 2 O 7 2− and Fe 3+ ions where H‐bonding based cavities played an important role. Fluorescence quenching, competitive binding studies and binding parameters substantiated significant recognition of S 2 O 7 2− and Fe 3+ ions by both CPs.

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