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Catalyst‐Free and Solvent‐Free Facile Hydroboration of Imines
Author(s) -
Pandey Vipin K.,
Donthireddy Siva Nagendra Reddy,
Rit Arnab
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201901016
Subject(s) - hydroboration , chemistry , catalysis , steric effects , yield (engineering) , solvent , organic chemistry , hydrolysis , combinatorial chemistry , materials science , metallurgy
A facile process for the catalyst‐free and solvent‐free hydroboration of aromatic as well as heteroaromatic imines is reported. This atom‐economic methodology is scalable, compatible with sterically and electronically diverse imines, displaying excellent tolerance towards various functional groups, and works efficiently at ambient temperature in most of the cases, affording secondary amines in good to excellent yield after hydrolysis.