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Nickel‐Catalyzed Chemoselective Acetalization of Aldehydes With Alcohols under Neutral Conditions
Author(s) -
Subaramanian Murugan,
Landge Vinod G.,
Mondal Akash,
Gupta Virendrakumar,
Balaraman Ekambaram
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900908
Subject(s) - nickel , catalysis , reusability , substrate (aquarium) , chemistry , scope (computer science) , aldehyde , chemoselectivity , functional group , organic chemistry , combinatorial chemistry , computer science , polymer , software , programming language , oceanography , geology
Abstract A molecularly defined Ni II ‐complex catalyzing the chemoselective acetalization of aldehydes with alcohols under neutral conditions is reported. The reaction is general, efficient and showed a wide substrate scope (including aliphatic aldehydes) as well as excellent functional group tolerance. Reusability of the present nickel catalyst is also demonstrated.