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Rational Design of an Ionic Liquid‐Based Electrolyte with High Ionic Conductivity Towards Safe Lithium/Lithium‐Ion Batteries
Author(s) -
Zhang Shengjie,
Li Junhao,
Jiang Ningyi,
Li Xuqiu,
Pasupath Sivakumar,
Fang Yanxiong,
Liu Quanbing,
Dang Dai
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900581
Subject(s) - ionic liquid , electrolyte , lithium (medication) , ionic conductivity , electrochemistry , materials science , ion , conductivity , salt (chemistry) , solvent , inorganic chemistry , chemical engineering , chemistry , organic chemistry , electrode , catalysis , medicine , engineering , endocrinology
It is a very urgent and important task to improve the safety and high‐temperature performance of lithium/lithium‐ion batteries (LIBs). Here, a novel ionic liquid, 1‐(2‐ethoxyethyl)‐1‐methylpyrrolidinium bis(trifluoromethylsulfonyl)imide (PYR 1(2o2) TFSI), was designed and synthesized, and then mixed with dimethyl carbonate (DMC) as appropriate solvent and LiTFSI lithium salt to produce an electrolyte with high ionic conductivity for safe LIBs. Various characterizations and tests show that the highly flexible ether group could markedly reduce the viscosity and provide coordination sites for Li‐ion, and the DMC could reduce the viscosity and effectively enhance the Li‐ion transport rate and transference number. The electrolyte exhibits excellent electrochemical performance in Li/LiFeO 4 cells at room temperature as well as at a high temperature of 60 °C. More importantly, with the addition of DMC, the IL‐based electrolyte remains nonflammable and appropriate DMC can effectively inhibit the growth of lithium dendrites. Our present work may provide an attractive and promising strategy for high performance and safety of both lithium and lithium‐ion batteries.