Catalytic C−H Borylation Using Iron Complexes Bearing 4,5,6,7‐Tetrahydroisoindol‐2‐ide‐Based PNP‐Type Pincer Ligand | Zendy

Kato Takeru | Zendy; Kuriyama Shogo | Zendy; Nakajima Kazunari | Zendy; Nishibayashi Yoshiaki | Zendy

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Catalytic C−H Borylation Using Iron Complexes Bearing 4,5,6,7‐Tetrahydroisoindol‐2‐ide‐Based PNP‐Type Pincer Ligand

Author(s) -

Kato Takeru,

Kuriyama Shogo,

Nakajima Kazunari,

Nishibayashi Yoshiaki

Publication year - 2019

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201900501

Subject(s) - borylation , anisole , pincer movement , chemistry , ligand (biochemistry) , catalysis , toluene , pyrrole , medicinal chemistry , pincer ligand , combinatorial chemistry , organic chemistry , aryl , receptor , biochemistry , alkyl

Catalytic C−H borylation has been reported using newly designed iron complexes bearing a 4,5,6,7‐tetrahydroisoindol‐2‐ide‐based PNP pincer ligand. The reaction tolerated various five‐membered heteroarenes, such as pyrrole derivatives, as well as six‐membered aromatic compounds, such as toluene. Successful examples of the iron‐catalyzed sp 3 C−H borylation of anisole derivatives were also presented.

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