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Catalytic Reactivity of Molybdenum–Trihalide Complexes Bearing PCP‐Type Pincer Ligands
Author(s) -
Eizawa Aya,
Arashiba Kazuya,
Egi Akihito,
Tanaka Hiromasa,
Nakajima Kazunari,
Yoshizawa Kazunari,
Nishibayashi Yoshiaki
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900496
Subject(s) - molybdenum , catalysis , trihalide , chemistry , reactivity (psychology) , iodide , pincer movement , ligand (biochemistry) , pincer ligand , ammonia , inorganic chemistry , medicinal chemistry , combinatorial chemistry , organic chemistry , polymer chemistry , medicine , biochemistry , alternative medicine , receptor , pathology , halide
Abstract Molybdenum–iodide complexes bearing a PCP[1] ligand have been found to work as excellent catalysts toward ammonia formation under ambient reaction conditions among dinitrogen‐bridged dimolybdenum complexes and other molybdenum complexes bearing PNP and PCP[2] ligands.