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Supramolecular Light‐Harvesting Antennas of Metal‐Coordinated Bis(8‐Hydroxyquinoline)‐Substituted Porphyrin Networks
Author(s) -
Fujimoto Junko,
Hayashi Sari,
Kainuma Hideyuki,
Manseki Kazuhiro,
Udagawa Taro,
Miyaji Hidekazu
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900483
Subject(s) - 8 hydroxyquinoline , porphyrin , supramolecular chemistry , metal , photochemistry , materials science , chemistry , inorganic chemistry , organic chemistry , molecule
Artificial antenna complexes of metal‐coordinated bis(8‐hydroxyquinoline)‐substituted porphyrin networks that mimic antenna chromophores in plants were organized on titanium dioxide electrodes in photoelectrochemical cells. The generated photocurrents can be optimized according to the two ways of porphyrin self‐assembly due to the “antenna effect”: changing the number of assembled porphyrin monolayers and the number of generations of the metal‐coordinated porphyrin networks.