Premium
Hierarchically Porous Carbons Derived from Metal–Organic Framework/Chitosan Composites for High‐Performance Supercapacitors
Author(s) -
Zhong Shan,
Kitta Mitsunori,
Xu Qiang
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900318
Subject(s) - supercapacitor , materials science , calcination , chemical engineering , chitosan , porosity , electrolyte , microporous material , electrochemistry , specific surface area , carbon fibers , metal organic framework , aqueous solution , composite material , electrode , adsorption , composite number , chemistry , catalysis , organic chemistry , engineering
Hierarchically porous carbon materials with high surface areas are promising candidates for energy storage and conversion. Herein, the facile synthesis of hierarchically porous carbons through the calcination of metal–organic framework (MOF)/chitosan composites is reported. The effects of the chitosan (CS) additive on the pore structure of the resultant carbons are discussed. The corresponding MOF/chitosan precursors could be readily converted into hierarchically porous carbons (NPC‐ V , V= 1, 2, 4, and 6) with much higher ratios of meso‐/macropore volume to micropore volume ( V meso‐macro / V micro ). The derived carbon NPC‐2 with the high ratio of V meso‐macro / V micro =1.47 demonstrates a high specific surface area of 2375 m 2 g −1 , and a high pore volume of 2.49 cm 3 g −1 , as well as a high graphitization degree, in comparison to its counterpart (NPC) without chitosan addition. These excellent features are favorable for rapid ion diffusion/transport, endowing NPC‐2 with enhanced electrochemical behavior as supercapacitor electrodes in a symmetric electrode system, corresponding to a high specific capacitance of 199.9 F g −1 in the aqueous electrolyte and good rate capability. Good cycling stability is also observed after 10 000 cycles.