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Rational Design of a Carbon‐Boron Frustrated Lewis Pair for Metal‐free Dinitrogen Activation
Author(s) -
Zhu Jun
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201900010
Subject(s) - frustrated lewis pair , boron , chemistry , catalysis , transition metal , carbon fibers , lewis acids and bases , activation energy , nitrogen , metal , nanotechnology , combinatorial chemistry , materials science , organic chemistry , composite number , composite material
Molecular nitrogen (N 2 ) is abundant in the atmosphere and, found in many biomolecules, an essential element of life. The Haber–Bosch process, developed over 100 years ago, requires relatively harsh conditions to activate N 2 on the iron surface and generate ammonia for use as fertilizer or to produce other chemicals, leading to consumption of more than 2 % of the world's annual energy supply. Thus, developing “green” approaches for N 2 activation under mild conditions is particularly important and urgent. Here we demonstrate that a metal‐free N 2 activation could be favorable both thermodynamically and kinetically (with an activation energy as low as 9.1 kcal mol −1 ) by using a carbon‐boron formal frustrated Lewis pair, which is supported by high‐level coupled cluster calculations. Mechanistic studies reveal that aromaticity plays a crucial role in stabilizing both the transition state and the product. Our findings highlight the importance of a combination of an N‐heterocyclic carbene with a methyleneborane unit in metal‐free N 2 activation, providing conceptual guidance for experimental realization.