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Guest Solvent‐dependence of the Nanomechanical Response in Substituted Dihydropyrimidinone Crystals
Author(s) -
Bhandary Subhrajyoti,
Rani Gulshan,
Mangalampalli S. R. N. Kiran,
Rao G. B. Dharma,
Ramamurty Upadrasta,
Chopra Deepak
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201801842
Subject(s) - materials science , solvent , composite material , chemistry , organic chemistry
The nanomechanical responses of two crystalline phases of a dihydropyrimidine analogue ( 1 ) were similar irrespective of the presence (or absence) of the guest solvent. In contrast, the mechanical responses of two differently solvated forms of the second related ( 2 ) crystals were significantly different. These contrasting behaviors are rationalized in terms of intermolecular interactions and energy distributions.