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Cover Feature: Bis‐copper(II) Complex of Triply‐linked Corrole Dimer and Its Dication (Chem. Asian J. 10/2019)
Author(s) -
Ooi Shota,
Tanaka Takayuki,
Ikeue Takahisa,
Yamasumi Kazuhisa,
Ueta Kento,
Shimizu Daiki,
Ishida Masatoshi,
Furuta Hiroyuki,
Osuka Atsuhiro
Publication year - 2019
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201801590
Subject(s) - corrole , dication , dimer , copper , cover (algebra) , crystallography , chemistry , ligand (biochemistry) , molecule , photochemistry , organic chemistry , mechanical engineering , biochemistry , receptor , engineering
Copper complexes of corroles have recently been attracting much interest due to their ligand non‐innocent character and unique redox properties. In this paper, bis‐copper(II) complexes of a triply‐linked corrole dimer and its two‐electron oxidized species were prepared as highly planar molecules. Their structures and magnetic properties were comprehensively studied. In the cover art, the structures of corroles are printed on the coins, one of which is made of copper. In Japanese custom, coins are often donated to a wooden box, named Saisenbako, in the shrine. The background picture is Heian‐Jingu shrine located in Kyoto. More information can be found in the Full Paper by Takayuki Tanaka, Atsuhiro Osuka et al. on page 1771 in Issue 10, 2019 (DOI: 10.1002/asia.201801467).