Nitrosylruthenium Complexes as Polymerization Catalysts for Acrylonitrile in DMF | Zendy

Nagao Hirotaka | Zendy; MisawaSuzuki Tomoyo | Zendy; Tomioka Nozomi | Zendy; Ohno Haruna | Zendy; Rikukawa Masahiro | Zendy

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Nitrosylruthenium Complexes as Polymerization Catalysts for Acrylonitrile in DMF

Author(s) -

Nagao Hirotaka,

MisawaSuzuki Tomoyo,

Tomioka Nozomi,

Ohno Haruna,

Rikukawa Masahiro

Publication year - 2018

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201801095

Subject(s) - acrylonitrile , polyacrylonitrile , polymerization , polymer chemistry , catalysis , chemistry , molar mass distribution , dimethylformamide , bipyridine , polymer , organic chemistry , copolymer , solvent , crystal structure

Nitrosylruthenium complexes bearing two 2,2′‐bipyridine (bpy) or 2‐pyridinecarboxylate (pyc) ligands, [Ru(NO)X(bpy) 2 ] 3+ (X=CH 3 CN, CH 2 =CHCN, H 2 O, Cl, ONO 2 ) and [Ru(NO)(OH 2 )(pyc) 2 ] + , were used as catalysts for the polymerization of acrylonitrile in N , N ‐dimethylformamide (DMF) under air without initiators to obtain polyacrylonitrile (PAN) with a high molecular weight and a narrow molecular weight distribution.

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