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Cocrystallization of Imide‐Fused Corannulene Derivatives and C 60 : Guest‐Induced Conformational Switching and 1:1 Segregated Packing
Author(s) -
Lu RuQiang,
Wu Shuang,
Bao YueHua,
Yang LinLin,
Qu Hang,
Saha Mithu,
Wang XiaoYe,
Zhuo YouZhen,
Xu Binbin,
Pei Jian,
Zhang Hui,
Weng Wengui,
Cao XiaoYu
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201801086
Subject(s) - imide , corannulene , cocrystal , chemistry , structural motif , crystallography , stereochemistry , polymer chemistry , molecule , organic chemistry , hydrogen bond , biochemistry
A pair of interconvertible stereoisomers of imide‐fused corannulene derivatives was mixed with C 60 , which resulted in cocrystallization into a 1:1 segregated packing motif through concave–convex π–π interactions. Only one conformation was observed in the cocrystal owing to guest‐induced conformational switching. The 1D assemblies of the complex showed promising applications in organic electronics.