Premium
Cover Feature: Tuning the Electronic Properties and Acid‐Response Behavior of N‐Heteroacene‐Based π‐Conjugated Liquids by Changing the Number of π‐Conjugated Substituents (Chem. Asian J. 18/2018)
Author(s) -
Sato Yuika,
Mutoh Yuichiro,
Matsukuma Daisuke,
Nakagawa Makoto,
Kawai Takeshi,
Isoda Kyosuke
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201800999
Subject(s) - conjugated system , fluorescence , dissolution , thiophene , phase (matter) , materials science , phase transition , chemical engineering , photochemistry , polymer , chemistry , organic chemistry , thermodynamics , optics , physics , engineering
Two room‐temperature fluorescent π‐conjugated liquids based on a N‐heteroacene framework were designed and prepared with one or two thiophene rings. These liquid materials can be utilized as inks to be coated on substrates and displayed different electronic properties and rheology behavior; for example, fluorescent colors were light blue and blue, respectively. Moreover, dissolving various acids substances in these liquids gave rise to different fluorescent colors. Furthermore, when acids with lower p K a values were dissloved in these liquids, a phase transition occurred to a self‐organized liquid‐crystalline phase. More information can be found in the Full Paper by Kyosuke Isoda et al. on page 2619 in Issue 18, 2018 (DOI: 10.1002/asia.201800631).