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Low‐Bandgap Cs 4 CuSb 2 Cl 12 Layered Double Perovskite: Synthesis, Reversible Thermal Changes, and Magnetic Interaction
Author(s) -
Singhal Nancy,
Chakraborty Rayan,
Ghosh Prasenjit,
Nag Angshuman
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201800635
Subject(s) - halide , band gap , perovskite (structure) , chemistry , thermal stability , layered double hydroxides , materials science , crystallography , inorganic chemistry , optoelectronics , adsorption , organic chemistry
Double perovskites (DPs) with a generic formula A 2 M′(I)M III X 6 (A and M are metal ions, and X=Cl, Br, I) are now being explored as potential alternatives to Pb‐halide perovskites for solar cells and other optoelectronic applications. However, these DPs typically suffer from wide (≈3 eV) and/or indirect band gaps. In 2017, a new structural variety, namely layered halide DP Cs 4 CuSb 2 Cl 12 (CCSC) with bivalent Cu II ion in the place of M′(I) was reported, which exhibit a band gap of approximately 1 eV. Here, we report a mechanochemical synthesis of CCSC, its thermal and chemical stability, and magnetic response of Cu II d 9 electrons controlling the optoelectronic properties. A simple grinding of precursor salts at ambient conditions provides a stable and scalable product. CCSC is stable in water/acetone solvent mixtures (≈30 % water) and many other polar solvents unlike Pb‐halide perovskites. It decomposes to Cs 3 Sb 2 Cl 9 , Cs 2 CuCl 4 , and SbCl 3 at 210 °C, but the reaction can be reversed back to produce CCSC at lower temperatures and high humidity. A long‐range magnetic ordering is observed in CCSC even at room temperature. The role of such magnetic ordering in controlling the dispersion of the conduction band, and therefore, controlling the electronic and optoelectronic properties of CCSC has been discussed.