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Hierarchical MoS 2 @TiO 2 Heterojunctions for Enhanced Photocatalytic Performance and Electrocatalytic Hydrogen Evolution
Author(s) -
Dong Yu,
Chen ShengYou,
Lu Yi,
Xiao YuXuan,
Hu Jie,
Wu SiMing,
Deng Zhao,
Tian Ge,
Chang GangGang,
Li Jing,
Lenaerts Silvia,
Janiak Christoph,
Yang XiaoYu,
Su BaoLian
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201800359
Subject(s) - photocatalysis , heterojunction , materials science , electrocatalyst , chemical engineering , hydrogen , hydrogen production , nanotechnology , optoelectronics , electrochemistry , catalysis , chemistry , electrode , engineering , biochemistry , organic chemistry
Hierarchical MoS 2 @TiO 2 heterojunctions were synthesized through a one‐step hydrothermal method by using protonic titanate nanosheets as the precursor. The TiO 2 nanosheets prevent the aggregation of MoS 2 and promote the carrier transfer efficiency, and thus enhance the photocatalytic and electrocatalytic activity of the nanostructured MoS 2 . The obtained MoS 2 @TiO 2 has significantly enhanced photocatalytic activity in the degradation of rhodamine B (over 5.2 times compared with pure MoS 2 ) and acetone (over 2.8 times compared with pure MoS 2 ). MoS 2 @TiO 2 is also beneficial for electrocatalytic hydrogen evolution (26 times compared with pure MoS 2 , based on the cathodic current density). This work offers a promising way to prevent the self‐aggregation of MoS 2 and provides a new insight for the design of heterojunctions for materials with lattice mismatches.

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