Ruthenium Complexes for Catalytic Dehydrogenation of Hydrazine and Transfer Hydrogenation Reactions | Zendy

Awasthi Mahendra Kumar | Zendy; Tyagi Deepika | Zendy; Patra Soumyadip | Zendy; Rai Rohit Kumar | Zendy; Mobin Shaikh M. | Zendy; Singh Sanjay Kumar | Zendy

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Ruthenium Complexes for Catalytic Dehydrogenation of Hydrazine and Transfer Hydrogenation Reactions

Author(s) -

Awasthi Mahendra Kumar,

Tyagi Deepika,

Patra Soumyadip,

Rai Rohit Kumar,

Mobin Shaikh M.,

Singh Sanjay Kumar

Publication year - 2018

Publication title -

chemistry – an asian journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.18

H-Index - 106

eISSN - 1861-471X

pISSN - 1861-4728

DOI - 10.1002/asia.201800315

Subject(s) - dehydrogenation , hydrazine (antidepressant) , ruthenium , catalysis , chemistry , combinatorial chemistry , photochemistry , organic chemistry , chromatography

Catalytic dehydrogenation of hydrazine was achieved over iminopyridine ligated ruthenium–arene complexes, where the release of H 2 gas, as confirmed by GC‐TCD, from hydrazine depends on reaction temperature, base, and solvents. NMR and MS studies indicated an in situ generation of a hydrazine‐coordinated ruthenium species, a key intermediate of hydrazine dehydrogenation, via a coordination‐assisted activation pathway.

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