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Synthetic Applications of Transition‐Metal‐Catalyzed C−P Bond Cleavage
Author(s) -
Wang Lili,
Chen Hui,
Duan Zheng
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201800307
Subject(s) - organic synthesis , transition metal , catalysis , nanotechnology , chemistry , carbon fibers , bond cleavage , combinatorial chemistry , materials science , organic chemistry , composite number , composite material
The wide occurrence of carbon–phosphorus bond activation in modern organic synthesis, catalyst deactivation, and biological process has attracted interest for synthetic applications. Over the past few decades, transition‐metal‐mediated transformations have become extremely powerful tools in organic synthesis. In this review, considerable progress that has been made in catalytic activations and transformations of carbon–phosphorus bonds within the coordination sphere of transition metals is described. Mechanistic information is also presented, and it is hoped that this review not only provides an account of the state of the art in the field, but also highlights the future potential of these reactions in organic synthesis.