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Visible‐Light‐Promoted Synthesis of 1,4‐Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides
Author(s) -
Wang ChaoMing,
Song Dan,
Xia PengJu,
Wang Jing,
Xiang HaoYue,
Yang Hua
Publication year - 2018
Publication title -
chemistry – an asian journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.18
H-Index - 106
eISSN - 1861-471X
pISSN - 1861-4728
DOI - 10.1002/asia.201701738
Subject(s) - conjugate , photocatalysis , chemistry , visible spectrum , aryl , combinatorial chemistry , scope (computer science) , chloride , organic chemistry , catalysis , materials science , mathematics , computer science , mathematical analysis , alkyl , optoelectronics , programming language
A facile visible‐light photocatalytic conjugate addition to prepare 1,4‐dicarbonyl compounds has been developed by employing readily available aroyl chlorides as aryl radical sources. This operationally simple method shows a broad scope with regard to both aroyl chlorides and Michael acceptors. As a result, a variety of 1,4‐diketones were efficiently synthesized in moderate to good yields.